Infopaket

Coordination chemistry

ВКБ.4.01

Вибіркова дисципліна для ОП

First

2023/2024

5 Semester

3

Р03. Skill to describe chemical data in symbolic form. Р04. Knowledge to understand basic patterns and types of chemical reactions as well as their characteristics. Р05. Knowledge to understand the relationship between structure and properties of substances. Р14. Skill to perform experimental work to test hypotheses and investigation of chemical phenomena and regularities. Р18. Ability to demonstrate knowledge and understanding of main facts, concepts, principles, and theories in chemistry. Р23. Skill to present competently research results using state and foreign languages, taking into account the purpose of communication.

Full-time form

The discipline "Coordination Chemistry" is based on the knowledge gained during the study of courses "General Chemistry", "Inorganic Chemistry", "Quantum Chemistry", and, in turn, is the basis for studying courses such as: "Spectroscopy of inorganic compounds", "Physical methods of research of inorganic compounds" "Bioinorganic chemistry", as well as necessary for students in the performance and writing of theses, the topics of which are related to the synthesis and study of coordination compounds.

The program of the course "Coordination Chemistry" includes a review of theories of coordination from the basic tenets of Werner's theory to modern views from the standpoint of ligand field theory. The introductory section is devoted to the material on the classification and nomenclature of coordination compounds. The simplest methods of detection of the inner sphere and extraspherical ions in coordination compounds, classification of ligands, their dentition are considered. Attention is paid to the concept of coordination number, its spatial interpretation, as well as factors that affect the value of the coordination number. The issues of the kinetics of the complexation reaction, the division into inert and labile complexes, and the mechanisms of ligand substitution reactions are discussed. Attention is also paid to the practical use of coordination compounds.

1. V.V. Skopenko, L.I. Savranskyi. Coordination chemistry. - K.: Lybid, 1997. 2. Holub A.M., Skopenko V.V. Basics of coordination chemistry. - K.: Higher school, 1977. 3. Skopenko V.V., Zub V.Ya. , Frytsky I.O., Lampka R.D. Experimental methods in coordination chemistry. K.: VOC "Kyiv University", 2009. 4. Skopenko V.V., Tsivadze A.Yu., Savranskyi L.I., Harnovskyi A.D. Coordination Chemistry — IKC Academic Book, 2007 5. Lawrence, Geoffrey A. (2010). Introduction to Coordination Chemistry. Wiley.

Lectures (with the use of computer presentations), laboratory work, independent work

Semester control includes homework and tests. The evaluation is based on a 100-point scale. The maximum / minimum number of points that can be obtained by a student during the semester assessment is 60 points / 36 points. The final assessment is conducted in the form of an exam. The maximum / minimum number of points that can be obtained by a student in the exam is 40 points / 24 points.

Ukrainian