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Chemistry of macromolecular compounds

ОК.16

Обов’язкова дисципліна для ОП

First

2023/2024

5 Semester

2

P01. Understand key chemical concepts, basic facts, concepts, principles and theories related to natural and life sciences and earth sciences, as well as chemical technologies. P03. Describe chemical data in symbolic form. P04. Understand the basic laws and types of chemical reactions and their characteristics. P05. Understand the relationship between the structure and properties of substances. P08. Know the principles and procedures of physical, chemical, physico-chemical research methods, typical equipment and devices. P09. Plan and perform a chemical experiment, apply appropriate techniques and techniques for the preparation of solutions and reagents.

Full-time form

1. Know the basic concepts of organic chemistry. 2. Know the basic concepts of physical chemistry. 3. Have basic knowledge of general chemistry.

General characteristics of polymers. Flexibility of macromolecules and their geometric characteristics. The function of equilibrium size distribution of macromolecules. Relaxation phenomena in polymers. Relaxation states of amorphous polymers: vitreous (glassy), rubbery, viscous liquid (rubbery flow, and the viscous flow) and oriented states. Structure and phase transformations of polymers in the condensed state: general characteristics of phase transformations of polymers in the condensed state and approaches to their analysis; structure of polymers in the condensed state; processes of melting and crystallization of polymers, their features, mechanisms and kinetics. Multicomponent polymer systems - filled polymers. Two-component polymer-containing systems. Polymer solutions. Phase equilibria in the polymer-solvent system. Features of diluted, semi-diluted and concentrated polymer solutions. Polymer gels.

1. Nyzhnyk V.V., Nyzhnyk T.Yu. Physical chemistry of polymers. K., Phytosocial Center, 2009. 2. Boyd R.H., Smith G.D. Polymer dynamics and relaxation – CUP, 2007.-255 p. 3. Wolynes P.G., Lubchenko V. (Ed.) - Structural Glasses and Supercooled Liquids. Theory, Experiment, and Applications, 2012. 4. Brinson H.F., Brinson L.C. Polymer Engineering Science and Viscoelasticity. An Introduction. - New York: Springer US, 2015. - 482 p.; 5. Montgomery T. Shaw, William J. MacKnight – Introduction to Polymer Viscoelasticity – Wiley-Interscience, 2005.-316 p. 6. Mandelkern L. Crystallization of polymers. Equilibrium concepts. Volume 1-2, Cambridge University Press, 2002.

Lectures, Practical classes

Semester control includes homework, tests and defense of practical work. The evaluation is based on a 100-point system. The maximum / minimum number of points that can be obtained by a student during the semester assessment is 60 points / 36 points. The final evaluation is conducted in the form of a test. The maximum / minimum number of points that can be obtained by a student on a credit of 20 points / 14 points. The test is taken by students who did not score 60 points during the semester assessment.

Ukrainian