Infopaket

NMR in inorganic chemistry

ВБ.3.04

Вибіркова дисципліна для ОП

Second

2022/2023

2 Semester

6

P01. To know the scientific concepts and modern theories of chemistry, as well as the fundamental foundations of related sciences. P02. Deeply understand the main facts, concepts, principles, theories related to the subject area mastered during the master's program, use them to solve complex tasks and problems, as well as conduct research in the relevant field of chemistry. P03. Apply the acquired knowledge and understanding to solve new qualitative and quantitative problems of chemistry. P09. Collect, evaluate, and analyze the data needed to solve complex chemistry problems using appropriate data processing methods and tools. P10. Plan, organize and carry out experimental research in chemistry using modern equipment, competently process their results and draw reasonable conclusions. P14. Interpret experimentally obtained data and correlate them with relevant theories in chemistry.

Full-time form

"Physico-chemical methods of identification of inorganic compounds" is a component of the cycle of professional training of specialists of the educational and qualification level "master", it requires successful mastering of the courses "Inorganic chemistry", "Chemistry of coordination compounds", "Magnetochemistry" of separate sections of organic chemistry and basic knowledge in the field of NMR.

is an advanced course that provides an advanced level of knowledge in order to be well versed in the possibilities of NMR spectroscopy in the field of Inorganic Chemistry and to critically monitor scientific publications in this field of science. This course focuses primarily on the following topics - manifestation of spin-spin interaction in inorganic compounds, nuclear relaxation mechanisms in inorganic compounds, dynamic processes occurring in solutions with coordination compounds, NMR spectra on metal nuclei, paramagnetic compounds and NMR spectroscopy , CP MAS NMR spectroscopy.

1. Volovenko Yu.M., Turov O.V. Nuclear magnetic resonance. K.; Irpin, VTF "Perun", 2007 - 480 p. 2. Tarasov V.P., Privalov V.I. Magnetic resonance of heavy nuclei in the study of coordination compounds. "Structure of molecules and chemical bonding" K, 1989 - p.3-135. 3. Hausser K.H., Kalbitzer H.R. NMR in medicine and biology: molecular structure, tomography, in-vivo spectroscopy. Kyiv: scientific opinion 1993 – 259 p. 4. Figgis, B.N., Lewis, J. The Magnetic Properties of Transition Metal Complexes. Progress in Inorganic Chemistry; Volume 26, 1979, Wiley 5. Friebolin H. One- and two-dimensional NMR-Spektroskopie. VCH, Weinheim - 317 6. Derome A. Modern NMR Techniques for Chemistry Research. Pergamon Press, 1988 - 280 p. 7. Croasmun W.R, Carlson R.M.K Two Dimensional NMR Spectroscopy. Applications for Chemists and Biochemists. VCH Publishers, 1987 - 511 p. 8. Claridge T.D.V. Modern methods of high-resolution NMR in chemistry. Kyiv, 2006 – 350 p.

Lectures and practical classes, independent work.

Semester assessment: The maximum/minimum number of points that can be obtained by a student: 60 points / 36 points, namely: 1. Control work #1: PH 1.1, PH 1.2, PH 2.1 – 15/9 points. 2. Test work #2: PH 1.1, PH 1.2, PH 1.3, PH 2.1, PH 4.1, PH4.2 – 15/9 points. 3. Oral report with presentation: RN1.1, RN 1.2, RN 2.1, RN 3.1 RN 4.1 – 15/9 points. 3. Practical classes No. 1–15: RN 1.1, RN 1.2, RN 2.1, RN 3.1, RN 4.1 – 15/9 points. Final evaluation (in the form of an exam): The maximum/minimum number of points that can be obtained by a student: 40 points / 24 points. Learning outcomes that will be evaluated: PH 1.1, PH 1.2, PH 1.3, PH 2.1, PH 2.2. Form of conduct: written work. Types of tasks: one theoretical question for 10 points, 5 test questions for 20 points and 1 task for 10 points. To receive an overall positive grade in the discipline, the exam grade cannot be less than 24 points.

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