Infopaket

Mechanisms of polymerization processes

ВКБ.8.08

Вибіркова дисципліна для ОП

First

2021/2022

8 Semester

3

Р01. Knowledge to understand key chemical concepts, essential facts, concepts, principles, and theories relating to natural sciences Р04. Knowledge to understand basic patterns and types of chemical reactions as well as their characteristics. Р10. Skill to apply basic principles of thermodynamics and chemical kinetics to solve professional tasks. Р12. To know main synthesis pathways in organic chemistry, including f interconversion of functional group and formation of carbon-carbon, carbon-heteroatom bonds. Р15. Ability to use acquired knowledge and skills for calculation, displaying, and modeling of chemical systems and processes, as well as the processing of experimental data. Р18. Ability to demonstrate knowledge and understanding of main facts, concepts, principles, and theories in chemistry. Р20. Skill to interpret the experimental data and to correlate this data with corresponding theories in chemistry.

Full-time form

1. Have basic knowledge of general chemistry. 2. Know the program material of the basic course of organic chemistry at the bachelor's level. 3. Possess basic skills of laboratory techniques and basics of organic synthesis at the bachelor's program level.

The study of general characteristics and classifications of "living"/controlled radical polymerization methods is expected; theoretical foundations of NMP-, RAFT-, and ATRP-polymerization methods of vanilla monomers and the possibility of synthesis of functionalized macromolecules by methods of "living"/controlled radical polymerization, anionic and cationic polymerization of vinyl, heterocyclic monomers; polymerization on free ions and ion pairs; counterion effect; polymerization of cyclic compounds.

1. M.M. Bratychak, R.-T. Sikorsky "Fundamentals of synthesis and reactivity of high molecular weight compounds". Kind. "Lviv Polytechnic". Lviv: 2003 2. Yu.P. Hetmanchuk, M.M. Bratychak Chemistry and technology of polymers. Lviv. Kind. "Beskid Bit", 2006.-495 p. 3. Hetmanchuk Yu.P. Polymer chemistry. - K.: Kyiv University Publishing and Printing Center, 2008.-456 p.-ISBN 978-966-439-060-3. 4. Hetmanchuk Yu.P. Polymer chemistry. (Part 2. Ionic polymerization.) - Kyiv University, 2000. 5. Handbook of RAFT polymerization. Ed. Christopher Barner-Kowollik, 2008.-WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-558 p.-ISBN 978-3-527-31924-4. 6. Moad, G.; Rizzardo, E.; Thang, S. H. Acc. Chem. Res. 2008, 41, 1133. 7. Ezio Rizzardo and David H. Solomon On the Origins of Nitroxide Mediated Polymerization (NMP) and Reversible Addition] Fragmentation Chain Transfer (RAFT) //Aust. J. Chem. 2012, 65, 945–969.

Сombination of lectures and practical exercises

Semester control includes homework and tests. The evaluation is based on a 100-point scale. The maximum / minimum number of points that can be obtained by a student during the semester assessment is 60 points / 36 points. The final assessment is conducted in the form of an exam. The maximum / minimum number of points that can be obtained by a student in the exam is 40 points / 24 points.

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