Infopaket

NMR in inorganic chemistry

ВБ 3.2

Вибіркова дисципліна для ОП

Second

2024/2025

2 Semester

4

Know and understand the main properties of "unconventional" nuclei in NMR spectroscopy and their influence on the characteristics of the corresponding NMR spectrum. Know the theoretical foundations of two-dimensional NMR spectroscopy and the main types of two-dimensional NMR spectra in the study of inorganic compounds. Know and understand the main approaches to the study of dynamic processes in solutions of coordination compounds by NMR. Know the theoretical foundations of obtaining NMR spectra of compounds in the condensed state. Be able to conduct a literature search, systematize and critically analyze the obtained NMR spectral data, and present the results of their research. Be able to use the knowledge gained to plan and set up NMR experiments in the study of inorganic compounds. Have the skills of public speaking and conducting discussions with colleagues and the target audience.

External form

2.1. Know the basics of high-resolution NMR spectroscopy, the nature of the occurrence of SSR and the relaxation pathways of an excited system of nuclei. 2.2. Be able to interpret one-dimensional NMR spectra of organic compounds, analyze the position, multiplicity and half-width of signals. 2.3. Be proficient in computer programs related to the processing of SSR and the presentation of the results of NMR experiments. 2.4. Be skilled in searching for the necessary information in scientific literature, scientometric databases and the Internet.

The academic discipline "NMR in Inorganic Chemistry" allows you to understand modern approaches to the identification and study of inorganic and coordination compounds by one- and two-dimensional NMR spectroscopy in solutions and NMR spectroscopy in the solid state. Examples of the use of 2D NMR spectroscopy in the study of the structure of complexes and their dynamic transformations in solutions are considered. A review of the NMR spectral characteristics of metal nuclei is provided. The basics of solid-state NMR spectroscopy and its capabilities for the study of condensed systems are revealed.

1. Воловенко Ю.М., Туров О.В. Ядерний магнітний резонанс. К.; Ірпінь, ВТФ «Перун», 2007 – 480 с. 2. Paul S.Pregosin. NMR in Organometallic Chemistry. Wiley-VCH, 2012, 392 p. 3. Jaz´winski Ja. Advances in understanding and use of NMR scalar couplings. Annual Reports on NMR Spectroscopy, Volume 107, 2022, pp. 185-254 4. Jonathan Ainsley Iggo and Konstantin V. Luzyanin. Nuclear Magnetic Resonance Spectroscopy, https://doi.org/10.1016/B978-0-08-102688-5.00002-7 5. NMR Spectroscopy, Second Edition. Basic Principles, Concepts and Applications in Chemistry. Edited by Harald Gunther (University of Siegen). John Wiley & Sons, New York, NY. 1995. 581 p

Lectures, laboratory work, independent work

Semester control includes two module tests (remotely), evaluation of literature search and laboratory reports. Evaluation is carried out on a 100-point system. Final assessment in the form of an exam. The maximum/minimum number of points that a student can receive during the semester assessment is 100 points/60 points.

Ukrainian